应用六氯化苯测年法对厦门港现代沉积速率的测定   总被引：2，自引：0，他引：2       下载免费PDF全文

林敏基  李木荣  许永水 《海洋与湖沼》1993,24(3):325-331

岩芯柱样用静力岩芯采样器于1986年采自福建省厦门港一九龙江口海域。通过对这些岩芯柱样中六氯化苯(BHC)的垂直分布状况和生物扰动类型的分析,应用 S_R=D_(BHC-D_(mix)/Y的计算模式,获得了这些岩芯的现代沉积速率数据。将这些数据、方法与原理完全不同的~(210)Pb放射性同位素测年法同岩芯测年数据比较,其结果在数据和数量级上有一定可比性。初步认为,再经进一步探索和改进,BHC测年法有可能应用于近岸河口港湾几十年来现代沉积速率的测定而与其它测年法互为补充。  相似文献   

Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios   总被引：1，自引：0，他引：1  

Man-Sik Choi  Hi-Il Yi  Shou Ye Yang  Chang-Bok Lee  Hyun-Ju Cha 《Marine Chemistry》2007

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.  相似文献   

Pb and other ore metals in modern seafloor tectonic environments: Evidence from melt inclusions   总被引：1，自引：0，他引：1  

Yannick Beaudoin  Steven D. Scott  Zoltan Zajacz 《Marine Geology》2007,242(4):271-289

Many modern seafloor tectonic environments are host to hydrothermal systems and associated polymetallic sulfide deposits. Metal transport and precipitation are controlled by magmatic processes such as pre-eruptive degassing and the hydrothermal cycle. The original availability of Pb and other ore metals in a given setting is dependent on concentrations in the original magmatic source or additional enrichment processes. We have examined the Pb budget of melt inclusions from nine modern seafloor settings representing back-arcs, mid-ocean ridges and seamounts. Melt inclusions provide information on the characteristics of parental magmas, including insights into metal budgets. Trace element data in melt inclusions hosted in plagioclase, olivine and pyroxene were obtained by laser-ablation inductively-coupled mass-spectrometry.Results from back-arcs emphasize the impact of slab-subduction and dehydration processes on the chemical characteristics of generated magmas. Volatile- and fluid-mobile element-rich melt inclusions at Manus basin and Okinawa trough reflect a robust contribution of elements from the subducting slab as evidenced by relatively low Ce/Pb ratios. At Bransfield strait, on the other hand, melt inclusions are volatile poor, and fluid-mobile element ratios are similar to mid-ocean ridge values indicating little or no contribution from the slab. High Cu concentrations at Manus basin and Okinawa trough can be explained by fluxing of ferric iron from the subducting slab benefiting the production of sulfate over sulfide.Metal budgets for seamounts located on and nearby the axis of mid-ocean ridge segments appear to be independent of any input of mantle plume material. Results from the southern Explorer ridge (strong lower mantle influence, transitional- and enriched-MORBs), Pito and Axial seamounts (moderate lower mantle influence, transitional-MORBs) and a Foundation near-ridge seamount (little to no mantle influence, normal-MORB) show that, despite similar tectonic environments and varying contributions of mantle plume material, Cu, Zn and Pb values do not vary significantly between the enriched and non-enriched magma components of a given setting.  相似文献   

LEADAT: a MATLAB-based program for lead-210 data analysis of sediment cores   总被引：3，自引：0，他引：3  

LU Xueqiang  MATSUMOTO Eiji 《海洋学报(英文版)》2006,25(6):128-137

1Introduction Tracking the history of man s impact on the en-vironment, it is clear that in many places the periodof greatest impact and most dramatic transformationlies within the last 150 a (Oldfield and Appleby,1984). Many aspects of this impact can be…  相似文献   

杭州湾南岸潮滩的~(210)Pb分布及其沉积学意义   总被引：1，自引：0，他引：1  

李炎  G.W.Berger  Tj.C.E.vanWeering 《海洋学研究》1993,(1)

杭州湾南岸潮滩的~(210)Pb垂向分布具有随深度波动的特征。湖滩颗粒物在吸附模拟系统中的~(210)Pb分配系数,主要受颗粒物含量的影响。本文从潮滩沉积~(210)Pb初始比度在低于平衡点一侧波动的机理,以及被沉积间断所分隔的有效封闭段的存在出发,提出选择常态沉积层的高~(210)Pb比度窗口,建立以CIC模式估计潮滩沉积速率的方法。  相似文献   

光释光测年中石英样品提纯方法的改进   总被引：1，自引：0，他引：1  

李国强  赵晖  范育新  彭海梅  陈发虎 《地球科学进展》2008,23(3):284-289

为了解决光释光前处理中遇到的传统方法无法获得满足纯度石英的问题,通过大量对比实验,结合玻璃工艺中石英分离研究成果,最后获得了新的石英提纯流程,与传统方法相比,新方法通过化学分离避免了密度变化对石英长石分离的影响,从而解决了斜长石和岩屑在传统的重液分离中无法剔除的问题,新方法能够获得满足纯度要求和量要求的石英,同时,新方法比传统方法实验室工作效率更高。  相似文献   

基于矿物学方法评价浙江省土壤中Pb污染状况     

郑喜珅  鲁安怀  汪庆华  郑佳  朱朝晖  于芳 《地质科技情报》2008,27(3):77-82

利用土壤重金属元素环境质量矿物学评价方法,对淅江省全境土壤中不同土壤类型(或亚类)表层、不同母质表层和剖面中的Pb进行环境质量评价的结果表明,土壤中Pb的实测量和土壤对Pb的固持量决定了土壤中Pb的环境质量,浙江省土壤中Pb的污染度有正负值,说明土壤中的Pb对有些地区产生了污染,而对有些地区则没有产生污染.研究结果揭示,土壤矿物对Pb具有一定的固定与容纳能力,超过其固定与容纳能力,土壤中的Pb会对环境造成污染.这一旨在揭示土壤中重金属元素与各种矿物之间环境平衡关系的方法,可为评价土壤环境质量提供科学依据和技术支撑.  相似文献   

成都经济区黄壤土壤剖面Pb形态分布特征及其影响因素   总被引：3，自引：1，他引：2  

杨晓燕  侯青叶  杨忠芳  杨艳  赵志丹 《现代地质》2008,22(6)

土壤剖面中不同形态铅迁移转化及其影响因素的研究对于了解Pb的土壤地球化学行为具有非常重要的意义。以四川省成都经济区农田生态系统黄壤剖面中不同形态Pb分布特征为例,探讨黄壤剖面中不同形态Pb的迁移转化影响因素及其生态危害性。结果表明:在黄壤剖面中,Pb总量表现为表层富集、深层稳定的特点;弱有机结合态含量表现为表层富集、深层稳定的特点,其他形态Pb含量剖面分布特征不明显;土壤中的Pb主要是以铁锰氧化态和残渣态为主,其他形态Pb含量所占比例较小;成土过程中,随着Pb总量的增加,稳定态Pb含量增加,而活动态相对减少;土壤pH值对各形态Pb含量分布影响较大,尤其是对碳酸盐结合态的影响显著;土壤总有机碳也是影响土壤中各形态Pb含量分布的重要因素之一,尤其是对有机结合态Pb含量影响显著;而随着土壤熟化程度的增加,黄壤剖面中的活动态含量增加,稳定态减少;剖面中的Pb迁移系数和生物可利用系数均较小,说明Pb不易向下迁移,容易在表层富集,对植物及人类有一定的危害。  相似文献   

热液锆石U-Pb定年与石英脉型金矿成矿时代:评述与展望   总被引：4，自引：0，他引：4  

毕诗健  李建威  赵新福 《地质科技情报》2008,27(1):69-76

石英脉型金矿床是最重要的金矿床类型之一,对其成矿时代的精确测定却一直是一道难题.近年来同位素质谱技术的发展使得通过含金石英脉中热液锆石的U-Pb定年来精确限定石英脉型金矿床成矿时代成为可能.但含金石英脉中的锆石组成通常较复杂,除有热液锆石外,还可能出现从围岩中捕获的岩浆锆石和变质锆石.锆石成因和组成的这种复杂性,经常导致所获得的U-Pb年龄数据难以解释或缺乏明确的地质意义.因此石英脉型金矿床锆石U-Pb定年的关键是有效区分从成矿流体中直接生长的热液锆石和从围岩中捕获的岩浆锆石或变质锆石.通过锆石形貌、结构、微量元素组成(含稀土元素)、矿物或流体包裹体特征等的系统分析和综合研究,可以较好地区分含金石英脉中的不同成因锆石.在此基础上利用先进的SHRIMP或LA-ICPMS锆石U-Pb分析技术对石英脉中的热液锆石进行微区原位定年,可以获得石英脉型金矿床可靠的成矿年龄.  相似文献   

西湖茶园茶叶铅污染铅同位素示踪     

郦逸根  路远发 《物探与化探》2008,32(2):180-185

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。  相似文献